Hybrid acrylic nanocomposites with excellent transparency and hardness/toughness balance
Authorized Users Only
2020
Authors
Stojanovic, DusicaBrajović, Ljiljana

Obradovic, Vera
Mijailovic, Daniel
Dramlic, Dragan
Kojovic, Aleksandar
Uskokovic, Petar
Article (Published version)

Metadata
Show full item recordAbstract
The composite nanofibers were used as reinforcement in acrylic polymer for the overall enhancement of thermomechanical
properties, adhesion between fibers and matrix, and fracture toughness of the final nanocomposite
since acrylic materials lack of this feature. So, a good balance between hardness/toughness and transparency is
obtained with the addition of poly (vinyl butyral) (PVB) and titania (TiO2) nanofibers simultaneously and
controlling their contents. Specifically, when compared to that of pure acrylic polymer, the fracture toughness of
the PMMA nanocomposite apparently increased 55 % with the addition of 3 wt.% titania nanoparticles, while
the produced nanocomposite maintained high transmittance above 75–80% in the visible domain. The transmission
spectrum modelling of the reinforced fiber materials and hybrid acrylic composites using Mie scattering
theory for different particle sizes and particle content is presented. The calculated transmission coefficients
versus wa...velength are compared with the experimental ones.
Keywords:
Composite nanofibers / Hybrid acrylic films / Mechanical and optical properties / Mie scattering modelSource:
Progress in Organic Coatings, 2020, 139, 105437-Publisher:
- Elsevier
Funding / projects:
- Predefined functional properties polymer composite materials processes and equipment development (RS-34011)
- Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-45019)
- Optoelectronics nanodimension systems - the rout towards applications (RS-45003)
DOI: 10.1016/j.porgcoat.2019.105437
ISSN: 0300-9440
WoS: 000519995900025
Scopus: 2-s2.0-85076228060
Institution/Community
GraFarTY - JOUR AU - Stojanovic, Dusica AU - Brajović, Ljiljana AU - Obradovic, Vera AU - Mijailovic, Daniel AU - Dramlic, Dragan AU - Kojovic, Aleksandar AU - Uskokovic, Petar PY - 2020 UR - https://grafar.grf.bg.ac.rs/handle/123456789/1946 AB - The composite nanofibers were used as reinforcement in acrylic polymer for the overall enhancement of thermomechanical properties, adhesion between fibers and matrix, and fracture toughness of the final nanocomposite since acrylic materials lack of this feature. So, a good balance between hardness/toughness and transparency is obtained with the addition of poly (vinyl butyral) (PVB) and titania (TiO2) nanofibers simultaneously and controlling their contents. Specifically, when compared to that of pure acrylic polymer, the fracture toughness of the PMMA nanocomposite apparently increased 55 % with the addition of 3 wt.% titania nanoparticles, while the produced nanocomposite maintained high transmittance above 75–80% in the visible domain. The transmission spectrum modelling of the reinforced fiber materials and hybrid acrylic composites using Mie scattering theory for different particle sizes and particle content is presented. The calculated transmission coefficients versus wavelength are compared with the experimental ones. PB - Elsevier T2 - Progress in Organic Coatings T1 - Hybrid acrylic nanocomposites with excellent transparency and hardness/toughness balance SP - 105437 VL - 139 VL - 139 DO - 10.1016/j.porgcoat.2019.105437 ER -
@article{ author = "Stojanovic, Dusica and Brajović, Ljiljana and Obradovic, Vera and Mijailovic, Daniel and Dramlic, Dragan and Kojovic, Aleksandar and Uskokovic, Petar", year = "2020", abstract = "The composite nanofibers were used as reinforcement in acrylic polymer for the overall enhancement of thermomechanical properties, adhesion between fibers and matrix, and fracture toughness of the final nanocomposite since acrylic materials lack of this feature. So, a good balance between hardness/toughness and transparency is obtained with the addition of poly (vinyl butyral) (PVB) and titania (TiO2) nanofibers simultaneously and controlling their contents. Specifically, when compared to that of pure acrylic polymer, the fracture toughness of the PMMA nanocomposite apparently increased 55 % with the addition of 3 wt.% titania nanoparticles, while the produced nanocomposite maintained high transmittance above 75–80% in the visible domain. The transmission spectrum modelling of the reinforced fiber materials and hybrid acrylic composites using Mie scattering theory for different particle sizes and particle content is presented. The calculated transmission coefficients versus wavelength are compared with the experimental ones.", publisher = "Elsevier", journal = "Progress in Organic Coatings", title = "Hybrid acrylic nanocomposites with excellent transparency and hardness/toughness balance", pages = "105437", volume = "139, 139", doi = "10.1016/j.porgcoat.2019.105437" }
Stojanovic, D., Brajović, L., Obradovic, V., Mijailovic, D., Dramlic, D., Kojovic, A.,& Uskokovic, P.. (2020). Hybrid acrylic nanocomposites with excellent transparency and hardness/toughness balance. in Progress in Organic Coatings Elsevier., 139, 105437. https://doi.org/10.1016/j.porgcoat.2019.105437
Stojanovic D, Brajović L, Obradovic V, Mijailovic D, Dramlic D, Kojovic A, Uskokovic P. Hybrid acrylic nanocomposites with excellent transparency and hardness/toughness balance. in Progress in Organic Coatings. 2020;139:105437. doi:10.1016/j.porgcoat.2019.105437 .
Stojanovic, Dusica, Brajović, Ljiljana, Obradovic, Vera, Mijailovic, Daniel, Dramlic, Dragan, Kojovic, Aleksandar, Uskokovic, Petar, "Hybrid acrylic nanocomposites with excellent transparency and hardness/toughness balance" in Progress in Organic Coatings, 139 (2020):105437, https://doi.org/10.1016/j.porgcoat.2019.105437 . .