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dc.creatorRajaković, Ljubinka V.
dc.creatorMarković, Dana D.
dc.creatorRajaković-Ognjanović, Vladana
dc.creatorAntanasijević, Davor Z.
dc.date.accessioned2019-04-19T14:18:56Z
dc.date.available2019-04-19T14:18:56Z
dc.date.issued2012
dc.identifier.issn0039-9140
dc.identifier.urihttp://grafar.grf.bg.ac.rs/handle/123456789/466
dc.description.abstractThe analytical properties of an analytical method must be evaluated through validation protocols. Beside specificity and/or selectivity, linearity of calibration, repeatability and accuracy, the most important parameters are: LOD (limit of detection) and LOQ (limit of quantification). Through these limits, it is possible to define the smallest concentration of analyte that can be reliably detected and quantified. To establish these limits, an analyst should apply several estimation methods and test a large number of sample replicates. It is difficult to make a compromise between complex statistical programs and the simple analytical demand to have reliable analytical parameters. The differences and equivalency of estimation methods and approaches for analytical limits could be overcome by an experimental comparison. In this paper, the focus is the LOD of inductively coupled plasma-mass spectrometry (ICP-MS) measurements employed for the determination of arsenic. The current approaches for the calculation of the LOD are summarized and critically discussed.en
dc.publisherElsevier B.V.
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/43009/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172007/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Technological Development (TD or TR)/37010/RS//
dc.rightsrestrictedAccess
dc.sourceTalanta
dc.subjectLimit of detectionen
dc.subjectEstimation approachesen
dc.subjectArsenicen
dc.subjectICP-MSen
dc.titleReview: The approaches for estimation of limit of detection for ICP-MS trace analysis of arsenicen
dc.typearticle
dc.rights.licenseARR
dc.citation.epage87
dc.citation.other102: 79-87
dc.citation.rankM21
dc.citation.spage79
dc.citation.volume102
dc.identifier.doi10.1016/j.talanta.2012.08.016
dc.identifier.pmid23182578
dc.identifier.rcubconv_1604
dc.identifier.scopus2-s2.0-84870254856
dc.identifier.wos000312692000012
dc.type.versionpublishedVersion


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