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Transparent PMMA/silica nanocomposites containing silica nanoparticles coating under supercritical conditions

Authorized Users Only
2013
Authors
Stojanović, Dušica B.
Brajović, Ljiljana
Orlović, Aleksandar
Dramlić, Dragan
Radmilović, Velimir
Uskoković, Petar S.
Aleksić, Radoslav
Article (Published version)
Metadata
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Abstract
This work reports the preparation of PMMA/silica nanocomposites with high optical transparency and enhanced mechanical properties using a melt compounding method. The surface of SiO2 particles was modified with a gamma-methacryloxypropyltrimethoxy silane coupling agent in a supercritical carbon dioxide-ethanol mixture and by conventional procedure. Dispersion of silica nanoparticles in ethanol at low temperatures plays an important role in deagglomeration and dispersion of nanosilica, which leads to the optimal particle-matrix bonding in composites. The optimal mechanical and optical properties were found for composites loaded with 5 wt% silica nanoparticles treated under supercritical coating method.
Keywords:
Nanocomposites / Supercritical coating / Microhardness / Mechanical and optical properties
Source:
Progress in Organic Coatings, 2013, 76, 4, 626-631
Funding / projects:
  • Predefined functional properties polymer composite materials processes and equipment development (RS-34011)
  • Reinforcing of Nanotechnology and Functional Materials Centre (EU-245916)

DOI: 10.1016/j.porgcoat.2012.12.002

ISSN: 0300-9440

WoS: 000316425000015

Scopus: 2-s2.0-84874117165
[ Google Scholar ]
45
41
URI
https://grafar.grf.bg.ac.rs/handle/123456789/535
Collections
  • Radovi istraživača / Researcher's publications
  • Катедра за математику, физику и нацртну геометрију
Institution/Community
GraFar
TY  - JOUR
AU  - Stojanović, Dušica B.
AU  - Brajović, Ljiljana
AU  - Orlović, Aleksandar
AU  - Dramlić, Dragan
AU  - Radmilović, Velimir
AU  - Uskoković, Petar S.
AU  - Aleksić, Radoslav
PY  - 2013
UR  - https://grafar.grf.bg.ac.rs/handle/123456789/535
AB  - This work reports the preparation of PMMA/silica nanocomposites with high optical transparency and enhanced mechanical properties using a melt compounding method. The surface of SiO2 particles was modified with a gamma-methacryloxypropyltrimethoxy silane coupling agent in a supercritical carbon dioxide-ethanol mixture and by conventional procedure. Dispersion of silica nanoparticles in ethanol at low temperatures plays an important role in deagglomeration and dispersion of nanosilica, which leads to the optimal particle-matrix bonding in composites. The optimal mechanical and optical properties were found for composites loaded with 5 wt% silica nanoparticles treated under supercritical coating method.
T2  - Progress in Organic Coatings
T1  - Transparent PMMA/silica nanocomposites containing silica nanoparticles coating under supercritical conditions
EP  - 631
IS  - 4
SP  - 626
VL  - 76
DO  - 10.1016/j.porgcoat.2012.12.002
UR  - conv_1419
ER  - 
@article{
author = "Stojanović, Dušica B. and Brajović, Ljiljana and Orlović, Aleksandar and Dramlić, Dragan and Radmilović, Velimir and Uskoković, Petar S. and Aleksić, Radoslav",
year = "2013",
abstract = "This work reports the preparation of PMMA/silica nanocomposites with high optical transparency and enhanced mechanical properties using a melt compounding method. The surface of SiO2 particles was modified with a gamma-methacryloxypropyltrimethoxy silane coupling agent in a supercritical carbon dioxide-ethanol mixture and by conventional procedure. Dispersion of silica nanoparticles in ethanol at low temperatures plays an important role in deagglomeration and dispersion of nanosilica, which leads to the optimal particle-matrix bonding in composites. The optimal mechanical and optical properties were found for composites loaded with 5 wt% silica nanoparticles treated under supercritical coating method.",
journal = "Progress in Organic Coatings",
title = "Transparent PMMA/silica nanocomposites containing silica nanoparticles coating under supercritical conditions",
pages = "631-626",
number = "4",
volume = "76",
doi = "10.1016/j.porgcoat.2012.12.002",
url = "conv_1419"
}
Stojanović, D. B., Brajović, L., Orlović, A., Dramlić, D., Radmilović, V., Uskoković, P. S.,& Aleksić, R.. (2013). Transparent PMMA/silica nanocomposites containing silica nanoparticles coating under supercritical conditions. in Progress in Organic Coatings, 76(4), 626-631.
https://doi.org/10.1016/j.porgcoat.2012.12.002
conv_1419
Stojanović DB, Brajović L, Orlović A, Dramlić D, Radmilović V, Uskoković PS, Aleksić R. Transparent PMMA/silica nanocomposites containing silica nanoparticles coating under supercritical conditions. in Progress in Organic Coatings. 2013;76(4):626-631.
doi:10.1016/j.porgcoat.2012.12.002
conv_1419 .
Stojanović, Dušica B., Brajović, Ljiljana, Orlović, Aleksandar, Dramlić, Dragan, Radmilović, Velimir, Uskoković, Petar S., Aleksić, Radoslav, "Transparent PMMA/silica nanocomposites containing silica nanoparticles coating under supercritical conditions" in Progress in Organic Coatings, 76, no. 4 (2013):626-631,
https://doi.org/10.1016/j.porgcoat.2012.12.002 .,
conv_1419 .

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